newsupernova/vendor/magento/module-multishipping/etc/config.xml

<?xml version="1.0"?>
<!--
/**
 * Copyright © Magento, Inc. All rights reserved.
 * See COPYING.txt for license details.
 */
-->
<config xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:noNamespaceSchemaLocation="urn:magento:module:Magento_Store:etc/config.xsd">
    <default>
        <multishipping>
            <options>
                <checkout_multiple>1</checkout_multiple>
                <checkout_multiple_maximum_qty>100</checkout_multiple_maximum_qty>
            </options>
        </multishipping>
    </default>
</config>